water-sensitive coating composition and absorbent article

专利摘要:
COMPOSITIONS OF COATINGS SENSITIVE TO THE Aqueous Medium FOR ACTIVATED RELEASE OF ACTIVE INGREDIENTS AND VISUAL INDICATION OF Aqueous Medium IN ABSORBENT ARTICLES, AND SUCH ARTICLES An absorbent article includes an upper layer, a lower layer and an absorbent central layer. The top layer, the central absorbent layer and the back layer each include a longitudinally directed peripheral side edge. The absorbent article further includes a coating composition sensitive to the aqueous medium for the triggered release of active ingredients from the absorbent article. The aqueous-sensitive coating composition is attached to the absorbent article adjacent to a longitudinally directed peripheral side edge. The coating composition includes a betaine ester or a betaine ester derivative having a functional active group derived from a fragrance with a hydroxyl group, a color-changing visual indication chemical, where the visual indication chemical is selected at from at least one group of a pH indicator dye and a pH adjuster, a thermochromic dye and a polarity sensitive dye.
公开号:BR112014011111B1
申请号:R112014011111-1
申请日:2012-11-07
公开日:2021-01-12
发明作者:Xuedong Song
申请人:Kimberly-Clark Worldwide, Inc.；
IPC主号:

专利说明:

[0001] [001] This application is a continuation in part of the application claiming priority in the copending U.S. Patent Application 13 / 292,612, entitled "Composition of non-adherent moisture indicator for application on polymeric substrate" submitted on November 9, 2011, on behalf by Ning Wei et al. FIELD OF THE INVENTION
[0002] [002] The present invention relates to humidity indicators involving a visual effect of color change or an olfactory change in response to the presence of an aqueous-based liquid. In particular, the invention relates to chemical compositions to provide such visual or olfactory moisture signals, as well as absorbent articles that have these moisture indicators attached or incorporated to them, which informs the caregiver or user of the product that the article is ready for immediate exchange or will need to be changed soon. HISTORIC
[0003] [003] The ability of a disposable absorbent article to detect moisture, dirt, or a change in state has been routinely recognized by manufacturers as a desirable feature for many modern hygiene products. Disposable absorbent items, such as diapers for children and babies and children's training pants; protectors, pants and underwear for adult incontinence; feminine hygienic products such as sanitary napkins, wipes, tampons and liners; cleaning products; mattress pads and the like, are highly absorbent and efficiently remove moisture from the surrounding environment. However, given the ability of these products to absorb large amounts of aqueous liquid, they can easily become saturated, much to the surprise of a product user or caregiver.
[0004] [004] In the case of disposable personal hygiene absorbent articles, which must be used together with the user's body, reducing skin irritation caused by prolonged exposure to moisture, it is a major concern. Since these items are so absorbent, users or caregivers may also not realize that the products have been soiled, especially if the top layer facing the user, and which is touched by the caregiver during use, may appear dry. If users are inexperienced children or disabled people who may not recognize the meaning of the bodily sensations associated with urination or dirt, they may also not be able to understand that a product needs to be changed. In any case, the saturation of such absorbent products can also eventually lead to product leakage and, subsequently, unpleasant and embarrassing odors and stains.
[0005] [005] In the case of discreet absorbent articles that cannot be easily seen by a consumer while using the product, except when undressing (such as sanitary towels), consumers may not appreciate the actual saturation level of a product, before an impending leak event. Thus, the caregiver or user may not recognize that the article is ready to be exchanged or that the leak may occur soon. The leakage of such discrete products can result in stains on underwear, normal clothing or bedding.
[0006] [006] The visual indicator mechanisms have therefore been used by manufacturers of absorbent consumer products for some time, to indicate the presence of moisture or a change in the condition of the absorbent articles. See, for example, JP2000- 279442, which describes an ink that changes color. A large number of moisture detection and visual indication technologies currently exist, including electronic humidity sensors, moisture indicators with color-changing ink, enzyme-based sensors or other chemicals that change the appearance after a change in the chemistry within of a product, indicators based on the change in pH and humidity indicators based on the change in temperature. Such moisture indicators typically provide a visual or audible indication of the article's dirtiness by means of a color change, by the disappearance or appearance of color or by the emission of a sound. Such moisture indicators may simply consist of water-soluble inks that disappear on contact with liquid moisture.
[0007] [007] Much of the previously described moisture sensing and signaling technology is often impractical for implementation in absorbent articles, since the technology is very expensive to implement in products of relatively lower cost. In addition, certain chemicals, such as enzyme-based moisture sensors, may have stability problems. Water-soluble dye-based moisture indicators also often do not have the high detection sensitivity desirable for use in newborn diapers. They can also provide insufficient color contrast, which sometimes makes reading the signal difficult. There is, therefore, a need for a practical technology of sensitive moisture indicator that can be easily implemented in a wide variety of absorbent articles.
[0008] [008] Although certain detection technologies based on color-changing inks have advanced, and are accessible for large-scale implementation in absorbent articles, such technologies may not be as effective for certain absorbent article applications where the physical location of a user and item placement prevents easy verification of a visual sensor. For example, although humidity indicators based on color-changing inks can easily be used for situations where a user is confined to a bed or other location, under the supervision of a caregiver, or where the article is readily visible, such as a exposed diapers of a child or baby sleeping or crawling, these technologies offer less advantage for absorbent feminine care articles, or for absorbent adult care articles for use by active adults, who are not readily visible and for whom discretion is of utmost importance to the user.
[0009] [009] Moisture indicators based on smell or fragrances have also been described to provide an alternative for visual indication of soiling of the article. For example, olfactory moisture signs are described in US2009 / 0221980 for Mosbacher et al. This reference describes the use of foul-smelling materials in an absorbent article, as well as the use of volatile esters to provide a pleasant aromatic odor through the degradation of encapsulation materials or a liquid moisture storage bag, encapsulation materials or of the bag being used to contain the volatile fragrance inside the absorbent article.
[0010] [0010] Fragrances are also often described for general use in absorbent articles to mask body odors such as sweat, urine, menstruation or bowel movements. However, fragrance indicators and masking components are often unstable due to their inherent volatility, such as those derived from essential oils. This chemistry often demonstrates a short shelf life and, as a result, presents issues of packaging, manufacturing and prolonged use. There is, therefore, a need for olfactory moisture indicators that do not depend only on packaging and storage containers (at an additional cost). There is still a need for such indicators that have a long useful life.
[0011] [0011] In an attempt to provide a controlled odor masking effect on urine in disposable sanitary products, US2008 / 0139378 for Hildebrand et al., Describes the use of non-volatile organopolysiloxane formulations to provide odor control functionality. Upon contact with urine, a fragrance alcohol is released by acid-catalyzed hydrolysis of functional betaine groups, which carry a radical of a fragrance alcohol in the organopolysiloxane molecule. As noted in the reference, the release of a fragrance alcohol occurs selectively in contact with acidic urine. Such functional groups are described as being more stable against hydrolysis at a neutral pH. Therefore, the use of such a high molecular weight chemistry in neutral or non-acidic environments is not described as providing fragrance functionality, and no other indicator technology is described as useful with such chemistry. In addition, organopolysiloxane chemistry is often used to impart hydrophobic attributes to products. As such, it poses challenges for use in absorbent articles, where hydrophobic chemistry significantly impacts the flow of aqueous liquids and absorption pathways. Such organopolysiloxane chemistry includes large polymer molecules, which are often expensive and can be difficult to put into solution. There is, therefore, a need for a controlled odor masking system that is easily released upon the occurrence of a soiling event (not the result of a relatively slow hydrolysis reaction), which does not significantly impede the absorption pathways and is easily soluble.
[0012] [0012] Combining several detection or moisture indication technologies with other chemical functionality is costly and presents practical challenges in the manufacture of the disposable absorbent article. In addition, the separate implementation of odor masking / signaling chemistry and visual moisture / coating indication technology adds further manufacturing steps. There is, therefore, a need for signaling technology for disposable absorbent articles that can provide multisensory signals of moisture and absorbent capacity to consumers, and that also mask the odors from body exudates.
[0013] [0013] Therefore, there is a need for a chemical coating technology that is relatively low cost and easy to apply in the manufacture of absorbent products, and that is capable of being combined with other chemical functionality to achieve the improved benefits, such as as capacity indicators. There is also a need for a relatively stable moisture indicator composition, which offers multiple signals in a single composition to a caregiver or consumer, which is not limited in its ability to be triggered by moisture pH chemistry, and which is not harmed by generally short shelf life common to volatile fragrances and essential oils. Finally, there is also a need for indicator composition systems, which offer relatively less interference with the absorption channels in an absorbent article. DESCRIPTIVE SUMMARY OF THE INVENTION
[0014] [0014] In general, the present description is directed to a multisensory coating composition sensitive to the aqueous medium, which can be used to coat various parts of an absorbent article for the purpose of indicating moisture and capacity. Such a coating composition provides a visual and olfactory warning of the soiling of the article and / or imminent leakage of the article. At the same time, the coating provides odor masking when an article is soiled by water-based body fluids, such as urine, vaginal secretions, menstruation, soft stools, or, alternatively, household spills containing liquid water.
[0015] [0015] In an embodiment of the invention, an aqueous-sensitive coating composition for the active release of active ingredients and visual indication of the presence of the aqueous medium from absorbent articles includes a betaine ester or betaine ester derivative , including a fragrance radical, which is derived from a fragrance alcohol with at least one hydroxyl group. The composition also includes a color-changing visual moisture indicator, which changes its color from a first color to a second color after a change of state, in which the color-changing visual moisture indicator includes at least one dye pH indicator and pH regulator, a thermochromic dye, and a polarity sensitive dye. In an alternative to this composition, the aqueous-sensitive coating composition includes at least one pH indicator dye and a pH regulator such as color-changing chemistry. In yet another alternative of this composition, the active ingredient is a fragrance radical group in the betaine ester or
[0016] [0016] derived from betaine ester, derived from a volatile fragrance alcohol, the radical of which is released from the betaine ester or derived from betaine ester through a hydrolysis reaction upon contact with an aqueous medium. In yet another alternative embodiment of the composition, the fragrance radical is derived from the group of fragrances selected from thymol, vanillin, menthol and eugenol. In yet another alternative embodiment of the composition, the composition includes at least one pH indicator dye, a pH regulator, a surfactant, and a binder.
[0017] [0017] In yet another alternative embodiment, the composition is applied to an absorbent article. In another alternative embodiment, the composition is applied to an absorbent article which includes at least an upper layer, a back layer and an absorbent central layer between the top layer and the back layer, and where the coating composition is applied to at least one top layer, back layer and central absorbent layer within the absorbent article. In yet another alternative embodiment, the absorbent article is any feminine hygiene article, an article for children and babies, an adult incontinence article, or a cleaning article in the form of an absorbent sheet. In yet another alternative embodiment, the coated absorbent article includes at least one peripheral side edge and the coating composition is located adjacent to at least one peripheral side edge. In another alternative embodiment, the layers within the absorbent article each include at least one peripheral side edge and the coating composition is applied to at least one layer and, adjacent to a peripheral side edge. In yet another alternative embodiment of the invention, the coated absorbent article includes at least a single central absorbent layer, wherein the central absorbent layer includes the coating composition.
[0018] [0018] In yet another alternative embodiment of the invention, the absorbent article includes a coating layer of the absorbent core that has a peripheral side edge and the coating composition is applied or attached to the layer of the absorbent core, at least adjacent to the edge peripheral side. In yet another alternative embodiment, the absorbent article and an upper layer, back layer and the central absorbent layer include an insulting central deposition zone (in a region between legs) and a peripheral side edge, and the coating composition is deposited, at least, in one of the central insulting deposition zones and on the peripheral lateral border.
[0019] [0019] In yet another alternative embodiment of the invention, a coated absorbent article includes at least an upper layer, a back layer and a central absorbent layer, wherein the moisture indicating coating composition is applied to at least one of the top, back and absorbent core layers. In yet another alternative embodiment of the invention, a coated absorbent article includes a peripheral side edge and the moisture indicating coating composition is applied to a part of the absorbent article adjacent the peripheral side edge.
[0020] [0020] In yet another alternative embodiment of the invention, the coated absorbent article includes an upper layer, back layer and central absorbent layer, each including at least one peripheral side edge, and the moisture indicating coating composition is applied adjacent at least one peripheral side edge of the top layer, back layer or central absorbent layer. In yet another alternative embodiment of the invention, the moisture indicating coating composition includes a color changing pH indicator dye, a pH regulator, and a betaine ester or betaine ester derivative with a functional derivative of a fragrance having at least one hydroxyl group. Alternatively, the coating composition includes a solvent, surfactant and binder.
[0021] [0021] In yet another alternative embodiment of the invention, an absorbent article coated with the composition includes at least two separate coating applications. In yet another alternative embodiment of the invention, the two separate coating applications are on two different layers within the absorbent article. In yet another alternative embodiment of the invention, the absorbent article includes longitudinally directed peripheral side edges and front and rear peripheral side edges and the coating composition is applied adjacent to at least one of the longitudinally directed peripheral side edges and front and rear peripheral edges . In another alternative embodiment, the coating composition is applied alongside two longitudinally directed peripheral side edges and peripheral front and rear edges.
[0022] [0022] In another alternative embodiment of the invention, an absorbent article comprises at least one central absorbent layer, where the absorbent article includes
[0023] [0023] I appeal less a longitudinally directed peripheral lateral border. The absorbent article includes an aqueous coating composition sensitive to the aqueous medium for the triggered release of active ingredients from the absorbent article, with the aqueous sensitive coating composition affixed to the absorbent article adjacent to the longitudinally directed peripheral side edge. The coating composition includes a betaine ester or derivative of betaine ester, including an active functional group; and a color change visual indicator chemistry, where the color change visual indicator chemistry is selected from at least one of the groups of a pH indicator dye and a pH adjuster, a thermochromic dye and a polarity sensitive dye.
[0024] [0024] In yet another alternative embodiment of the invention, an absorbent article comprises at least an upper layer, a back layer and an absorbent central layer. The top layer, the central absorbent layer and the back layer each include a longitudinally directed peripheral side edge. The absorbent article includes an aqueous-sensitive coating composition for the triggered release of active ingredients from the absorbent article. The aqueous-sensitive coating composition is attached to the absorbent article adjacent to at least one of the longitudinally directed peripheral side edges and includes a betaine or betaine ester derivative, including a functional active group derived from a fragrance with a hydroxyl group. ; a color indicator visual indicator chemistry, where the visual indicator chemistry is selected from at least one of the selected groups of a pH indicator and regulator and pH dye, a thermochromic dye and a polarity sensitive dye.
[0025] [0025] Other resources and aspects of this disclosure are discussed in more detail below. BRIEF ILLUSTRATION OF THE FIGURES
[0026] [0026] FIG. 1 is a rear perspective view of an embodiment of an absorbent article that has multisensory moisture signaling indicators according to the invention, the article in the form of a detached diaper.
[0027] [0027] FIG. 2 is a front perspective view of the diaper embodiment shown in Figure 1.
[0028] [0028] FIG. 3 is a plan view of the diaper embodiment shown in Fig. 1 with the diaper in a detached, unfolded and flat state, showing the surface of the article, which is facing the user (side facing the clothes).
[0029] [0029] FIG. 4 is a plan, cross-sectional view of an alternative embodiment of the diaper-absorbent article shown in Fig. 3, showing the surface of the article that is facing the wearer's skin when dressed.
[0030] [0030] FIG. 5 is an exploded perspective view of an alternative embodiment of an absorbent article of the present invention, in the form of a female hygienic protector, having multisensory moisture indicators shown in various positions of the article, adjacent to the peripheral side edges of the article, and several layers of peripheral side edges.
[0031] [0031] FIG. 6 is an exploded sectional view of the female sanitary pad of Fig. 5 taken along line 6-6.
[0032] [0032] FIG. 7 is a top perspective view of an alternative embodiment of an absorbent article of the present invention, in the form of an absorbent sheet with the inventive multisensory coating sensitive to the aqueous medium applied thereto.
[0033] [0033] The repeated use of reference characters in this specification and in the drawings presented is intended to represent characteristics or similar elements, or analogues, of the present invention. DETAILED DESCRIPTION OF THE INVENTION
[0034] [0034] In general, the present invention is directed to a multisensory coating composition sensitive to the aqueous coating medium for the triggered release of functional active ingredients in the form of fragrances, and for providing a visual indication of moisture. In particular, the coating composition is for the triggered release of functional active ingredients and visual indicators of absorbent articles. Such an aqueous-sensitive coating provides the "multisensory" indication of moisture or dirt in the absorbent article by means of a visual and olfactory indication of moisture in the absorbent article by an aqueous fluid, such as urine, menstrual flow, vaginal secretions, mucosa or feces. Depending on how the coating is used on an absorbent article, such a coating composition can be used both as an indicator of moisture / initial soiling and odor masking, as well as an indicator of capacity, indicating that the capacity of the absorbent article has been reached or that the article is about to leak.
[0035] [0035] Such a coating is triggered by contact with an aqueous medium, as opposed to moisture vapor. Therefore, it is less sensitive to activation by the mere exposure to air humidity. It is capable of being applied to an article, without requiring specialized encapsulation or packaging. In addition, the release of olfactory signs of moisture from the coating is not slow, since an aqueous medium has come into contact with the coating. For the purposes of this application, the term "aqueous medium" means a medium containing "liquid" water, instead of water vapor. This aqueous medium is exemplified by urine, vaginal secretions, mucosa, menstrual flow, liquid or loose stools, as well as household spills that contain water.
[0036] [0036] For the purposes of the present description, such an absorbent article may be a disposable absorbent article for personal care or hygiene. Such a personal care item can be for babies (child) or children, such as diapers, training pants, mattress pads or wipes, for example; for the care of feminine hygiene, such as sanitary napkins, diapers, linings, tampons or wipes, for example; for adult incontinence care, such as underwear inserts, pants, underwear, mattress pads or wipes. Alternatively, these absorbent articles can be for household use or for personal cleaning or disinfection, such as absorbent sheets of fabrics, towels or handkerchiefs. Other examples of absorbent articles that can benefit from such coatings include hospital gowns, surgical drapes and sterilization wrappers.
[0037] [0037] For the purposes of this description, such coating chemistry is a unique coating chemical composition that includes multisensory indicator components in a formula. Such multiple indicator components are multisensory, so that a user is informed in different ways when dirt occurs. The coating is applied to an absorbent article as a single composition, rather than multiple compositions applied at different times or locations. Such a singularly coated chemical composition is used to provide the functionality of visual moisture indicator, as well as the functionality of masking or odor signaling. Such a unique coating composition can be applied to one or more separate areas of an absorbent article. In one embodiment, as will be explained later, it is desirable that several separate applications of such a coating composition are physically separated from a single absorbent article, such that they are adjacent to several peripheral side edges of an absorbent article or an inner layer absorbent article.
[0038] [0038] Such multisensory indicator compositions can be used within disposable absorbent articles, particularly personal hygiene absorbent articles, to also provide indication of impending product leakage, through particular placement in locations within the absorbent articles (or layers within articles) that would come in contact with a liquid medium at a time before imminent leakage, such as at or near peripheral side edges of an article. In such a case, the coating composition would only be activated by initially soiling the edges of an article, or movement of liquid moisture from an aqueous medium in the article to locations adjacent to the peripheral side edge of the article or the article layer. Upon detecting the olfactory indicator (the smell of the volatile fragrance released after contact with liquid water), the consumer then understands that the dirt has spread to a place in the article where the leak may occur soon. As such, the composition would be useful as an indicator of capacity, rather than merely acting as an indicator of dirt.
[0039] [0039] For the purposes of this order, fragrances are considered functional "active" ingredients. As such, betaine esters with fragrance radicals can be considered precursors to active ingredients (or pro-fragrances). For the purposes of this application, the relevant betaine esters are changed with the addition of one or more groups of fragrance radicals which, when released, become volatile, such as when a dry coating composition (containing the betaine ester with radical fragrance) comes into contact with an aqueous medium. This aqueous medium can be of any pH value, for example, such as that found in vaginal excretions, urine, liquid faeces, menstruation, or other body excretion, such as a nasal discharge, as well as spills for domestic use.
[0040] [0040] Such multisensory coating composition includes at least one betaine ester or betaine ester derivative with a group of fragrance radicals, and a color-changing dye, desirably, a white dye, pH-altering dye, dye thermochromic or polarity sensitive dye. For the purposes of this application, the term "color change" refers to the change from a first color to a second color, such as from green to blue or blue to yellow, as opposed to the color that appears from a previously state non-colored or color that disappears to a non-colored state. The coating composition desirably also includes an organic solvent and, optionally, other components that would improve the functionality of the formulation, such as, for example, one or more developers (to intensify the color, depending on the type of ink or dye), desensitizers, one or more surfactants, one or more binders, and one or more pH regulators. Other components and additives may include ink preservatives and common fragrance additives that are well known in the art. Other additives can be used, such as to adjust the physical properties of the composition. For example, the composition may contain reagents to adjust the viscosity of the solution, or it may include chemicals to improve the composition's adhesion to certain substrate surfaces at the time of drying or cooling (in the case of a melted coating). The composition may further include chemical substances that adapt the subsequent wettability of the coating composition on the substrate surface. All of the above components are desirably dissolved together in a volatile organic solvent medium to form a homogeneous solution. In other embodiments, these materials can be combined in a hot melted coating.
[0041] [0041] For the purposes of this description, a suitable betaine ester should be described by the general formula:
[0042] [0042] The betaine ester is a betaine ester and a volatile fragrance with one or more hydroxyl groups. That is, the group (R) represents a radical of a volatile fragrance alcohol, with one or more hydroxyl groups. Desirably, part (R) is independently derived from a fragrance alcohol with more than four (4) carbon atoms of natural or synthetic origin; each R1, R2, R3, R4 and R5, independently, is selected from hydrogen, or organic parts such as alkyl, hydroxyalkyl, aryl, or aromatic groups, with n ≥ 1, preferably 2 or 3, and ≤ 4, because the higher the number "n", the lower the probability of rapid hydrolysis (therefore, the slower the fragrance will be released). Desirably, in one embodiment, groups R3-R5 include less than 8 carbon atoms in total, desirably with any group (R3, R4 or R5) including between 2-6 carbon atoms. In one embodiment, each of the R3-R5 groups is desirably a methyl group. X is a compatible anion. Such a component of the fragrance alcohol group (R) includes components with odorous properties. It must also be recognized that the higher the value of "n", the more difficult it is also for the betaine ester to be solubilized in water, as well as undergo hydrolysis. In addition, the smaller the groups from R1 to R5, the less stable the betaine ester with associated fragrance alcohol (R) will be, in the sense that the likelihood that vapor / moisture in the air alone will cause the dissociation of the group of fragrance alcohol of the betaine ester molecule. Furthermore, if the betaine ester is very hydrophobic, that is, if it includes large hydrophobic groups at the R3-R5 positions, or is part of a larger hydrophobic structure, it is more likely that it will not be soluble in water.
[0043] [0043] As noted, it is desirable that the betaine ester is not large, (does not include a number "n" greater than 4, which is not part of a larger polymer structure, and is not itself linked to a group functional, to a chain-based structure) in such a way that it can be easily solubilized, and not be so hydrophobic in nature to hinder processing, and affect the flow of aqueous liquid on a coated substrate. In addition, if the betaine ester is too large to include larger groups at its R3-R5 positions, or is part of a larger structure, it has been found that the hydrolysis reaction time is slower. In a desirable embodiment, such a betaine ester includes only hydrogen or alkyl carbon-based moieties in its R1- R5 groups.
[0044] [0044] In one embodiment, the functional asset (radical of the fragrance alcohol) of the group (R) is selected from the fragrance group comprising 4-allyl-2-methoxyphenol (eugenol), 3- (2- bornyloxy) -2-methyl-1-propanol, 2-tert-butylcyclohexanol, 4-tert-butylcyclohexanol, benzyl alcohol, 1-decanol, 9-decen-1-ol, dihydroterpineol, 2,4-dimethyl-4-cyclohexene- 1-yl methanol, 2,4-dimethylcyclohexyl methanol, 2,6-dimethyl-2-heptanol, 2,6-dimethyl-4-heptanol, 3a, 4,5,6,7,7a-hexahydro-2,4- dimethyl-4,7-methane [1H] inden-5-ol, 3,7-dimethyl-1,6-nonadien-3-ol, 2,6-dimethyl-2,7-octadien-6-ol (linalool) , cis-3,7-dimethyl-2,6-octadien-1-ol (nerol), trans-3,7-dimethyl-2,6-octadien-1-ol (geraniol), 3,7-dimethyl-1 , 7-octanediol, 3,7-dimethyl1-octanol (tetrahydrogeraniol), 2,6-dimethyl-2-octanol (tetrahydromyrcenol), 3,7-dimethyl-3-octanol (tetrahydrolinalool), 2,6-dimethyl-7- octen-2-ol (dihydromyrcenol), 3,7-dimethyl-6-octen-1-ol (citronellol), 2,2-dimethyl-3- (3-methylphenyl) -1- propanol, 2,2-dimethyl- 3-f enyl-1-propanol, 2-ethoxy-4-methoxymethylphenol, 2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol, cis-3- hexen-1-ol, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, 1-hydroxy-2- (1-methyl-1-hydroxyethyl) -5-methylcyclohexane, 3- (hydroxymethyl) -2- nonanone, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, isoborneol, 3-isocamphylcyclohexanol, 2-isopropenyl-5-methylcyclohexanol (isopulegol), 1- isopropyl-4-methylcyclohex-3-enol (terpinenol), 4-isopropylcyclohexanol, 1- (4- isopropylcyclohexyl) ethanol, 4-isopropylcyclohexilmethanol, 2-isopropyl-5-methylcyclohexanol (menthol), 2-isopropyl-5-methylphenyl (thymol), 5-isopropyl (carvacrol), 2- (4-methyl-3-cyclohexenyl) -2-propanol (terpineol), 2- (4-methylcyclohexyl) -2-propanol (dihydroterpineol), 4-methoxybenzyl alcohol, 2-methoxy-4-methylphenol , 3-methoxy-5-methylphenol, 1-methoxy-4-propenylbenzene (anethol), 2-methoxy-4-propenylphenol (isoeugenol), 4-methyl-3-decen-5-ol, 2-methyl-6-methylene -7-octen-2-ol (mircenol), 3-methyl-4-phenyl-2-but anol, 2- (2-methylphenyl) ethanol, 2-methyl-4-phenyl-1-pentanol, 3-methyl-5-phenyl-1-pentanol, 2-methyl-1-phenyl-2-propanol, (1- methyl-2- (1,2,2-trimethylbicyclo [3.1.0] hex-3-ylmethyl) cyclopropyl) methanol, 3-methyl-4- (2,2,6-trimethylcyclohexen-1-yl) -2-butanol , 2-methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol, (3-methyl-1- (2,2,3-trimethyl-3 - cyclopentenyl) -3-cyclohexen-1-yl) methanol, 3-methyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol, 2-methyl- 2-vinyl-5- (1-hydroxy-1-methylethyl) tetrahydrofuran, trans, cis-2,6-nonadienol, 1-nonanol, nopol, 1,2,3,4,4a, 5,6,7- octahydro - 2,5,5-trimethyl-2-naphthol, 1-octanol, 3,4,5,6,6-pentamethyl-2-heptanol, 2-phenylethanol, 2-phenylpropanol, 3-phenylpropanol (hydrodynamic alcohol), 3 -phenyl-2-propen-1-ol (cinnamic alcohol), 4- (5,5,6-trimethylbicyclo [2.2.1] hept-2-yl) cyclohexane-1-ol, 3,5,5-trimethylcyclohexanol, 2,4,6-trimethyl-4-cyclohexene-1-ylmethanol, 5- (2,2,3-trimethyl-3-cyclopentenyl) -3-methylpentane-2-ol, 3,7,11-trimethyl-2, 6,10-dodecatriene-1-ol (fa rnesol), 3,7,11- trimethyl-1,6,10-dodecatriene-3-ol (nerolidol), 3,5,5-trimethyl-1-hexanol (isononanol), 1-undecanol, 10-undecene-1 -ol, vetiverol.
[0045] [0045] In another desirable embodiment, the fragrance active group (R) in the betaine ester is derived from 2-phenoxyethanol, phenylethyl, geraniol, citronelol, 3-methyl-5-phenyl-1-pentanol, 2,4 -dimethyl-3-cyclohexene - 1-methanol, linalool, tetrahydrolinalool, 1,2-dihydromyrcenol, hydroxycitonelal, farnesol, menthol, eugenol, thymol, vanillin, cis-3-hexenol, terpineol and mixtures thereof.
[0046] [0046] An example of a particularly desirable fragrance active group (R) that is linked to the betaine ester is the eugenol radical. Eugenol itself is represented by the following formula:
[0047] [0047] Other particularly desirable (R) groups of volatile fragrance alcohols include the menthol and thymol radicals, with thymol which offer the additional advantage of providing the potential antibacterial functionality to the absorbent article in which it is coated. Although such fragile volatiles are actively volatile in their dissociated alcohol state, such volatility is eliminated once their radicals are attached as part of the betaine ester at the site (R).
[0048] [0048] "X" anions have no corrosive or notably irritating effect on human or animal skin, and are desirable for use in the coating, for association with the betaine ester. Anions are desirably chosen from the group consisting of chloride, bromide, methyl sulfate, ethyl sulfate, sulfate, nitrate, phosphate and hydrogen phosphate.
[0049] [0049] As noted, once the betaine ester with the fragrance radical fraction was synthesized, it was found that the (R) group is not volatile and is stable in the absence of an aqueous medium. This is especially the case for betaine esters, where R3-R5 include at least 8 carbon atoms in total in their structures. After introducing the betaine ester or betaine ester derivative into an aqueous medium, it undergoes a hydrolysis reaction in which the fragrance separates from the betaine ester and is released as an active fragrance volatile. This is illustrated by the following reaction:
[0050] [0050] The resulting by-products are carboxylic acid and a volatile fragrance alcohol (structure (R-OH)), with the latter released into the environment surrounding the article to produce the olfactory signal.
[0051] [0051] In an alternative embodiment, the betaine ester with the fragrance radical (R) can be further chemically encapsulated by a stimulus-sensitive matrix or reservoir, so that it is not released inadvertently, or is released intentionally more slowly , and only with the presence of a limit quantity of stimuli, such as a threshold value of aqueous medium of a certain pH level. Examples of matrix or reservoir materials include, but are not limited to, water soluble polymers, pH sensitive polymers, thermogels or a combination thereof as are known in the art.
[0052] [0052] In general, betaine esters, their derivatives, and their preparation are known and, as such, the synthesis steps of certain betaine esters with fragrance radical groups will no longer be outlined. However, examples of relatively smaller betaine ester molecules with fragrance radicals attached (groups of volatile alcohol radicals) can be found in U.S. Patent No. 5,958,870 to Declercq et al. and EP0752465 for Struillou, each of which is incorporated herein in its entirety for reference purposes. It has now been found, however, that such a chemistry is particularly suitable as a base chemistry for a unique indicator formulation for use as an indicator and olfactory moisture indicator coatings for absorbent articles, particularly if these betaine esters are limited in size. , do not require triggering by extreme pH changes, and do not have a serious impact on the absorption pathways, either as a result of their degree of hydrophobicity or the particular positioning within an absorbent article.
[0053] [0053] Alternatively, such betaine esters can be used with color-altering pH indicators to create moisture and capacity indicators for specific consumer absorbent products. For example, the understanding that different body fluids demonstrate certain pH ranges, visual pH sensitive indicators can be employed with such betaine esters on absorbent substrates, so that after being soiled by water based body fluids, visual indicators and wetting scents / capacity indicators can be triggered, offering sensitivity to a specific body exudate. As an example, the pH of urine and vaginal secretions often differ, and therefore, the pH indicator inks used with such betaine esters would be different to correlate with the pH of the respective body fluids.
[0054] [0054] Desirably, in one embodiment, the betaine ester or betaine ester derivative with the fragrance alcohol radical attached is present in the coating composition in an amount of about 0.1 and 30% by weight, alternatively between about 0.1 and about 20% by weight, even more alternatively, between about 1 to 10% by weight, even more alternatively, between about 2 and 10% by weight, even more alternatively, between about 2 and 5% by weight. These weight percentages, and all of the following weight percentages, are based on the total weight of the coating composition.
[0055] [0055] The aqueous-sensitive multisensory coating composition of the present invention desirably includes a non-aqueous or conductive liquid solvent to support the betaine ester or betaine ester derivative, visual indicator dye and other components of the formulation, given that contact with the aqueous liquid will result in the hydrolysis reaction. All components in the composition of the multisensory indicator are desirably soluble in one or more volatile organic solvents, such as the solvents used for flexographic printing and gravure printing. Suitable volatile organic solvents can include, for example, ethanol, methanol, propanol, isopropanol, butanol, acetone, tetrahydrofuran (THF), benzene and toluene, methylene chloride, chloroform or combinations thereof. When the multisensory visual and olfactory indicator component solution and an organic solvent is formed, it is a liquid at room temperature. The volatile organic solvent evaporates when the composition of the multisensory indicator is applied to a desired substrate. Volatile organic solvents can be present from about 20% by weight to about 90% by weight; generally between about 25, 30, or 35 to about 60, 70 or 80% by weight inclusive.
[0056] [0056] As such, the aqueous-sensitive coating composition is designed to present a visual and olfactory indication of soiling, and will also include an aqueous-triggerable dye, such that the appearance of the aqueous medium will trigger a color change. , from a first color to a second color, an appearance of color, where previously there was none, or the disappearance of a previously present color from the composition. In a desirable embodiment, the visual indicator is a color-changing dye, which changes from a first color to a second color. It should be noted, however, that these olfactory indicators can be properly used without the accompaniment of visual indicators in specific areas of an absorbent article, such as along the peripheral lateral edge of an article or layer, or within distances marked at from the peripheral side edges, in order to provide the capacity indication. Alternatively, such a multisensory indicator composition can be used at a first location on an absorbent article, and the same olfactory or other indicator, since it is included in the multisensory indicator composition, can be used at a second location, closer to the peripheral edge of the article or layer in the article. In this situation, when a different smell is detected (from a different olfactory indicator), the consumer would recognize that the leakage of the article is imminent.
[0057] [0057] The types of dyes to create the visual change of the visual indicator that are useful in the composition include leuco dyes, pH indicator dyes, thermochromic dyes, as well as polarity sensitive dyes. Color arising and disappearing dyes and product designs are described, for example, in U.S. Patent No. 6,307,119 for Cammarota and US Publication 20100030173 for Song et al., Which are hereby incorporated by reference in their entirety.
[0058] [0058] In one embodiment, it is desirable that such a dye be a leuco dye of color appearance. White dyes are generally referred to as colorless or light basic dyes, since dye molecules can take two forms, one of which is colorless. It is desirable that such leuco dyes be used in conjunction with developers. Although not intended to be limited by theory, the color-developing agent used with a leuco dye is believed to act as a Lewis acid, which removes electrons from the leuco dye molecule to generate a conjugate system. Thus, the leuco dye appears to manifest color from an initially colorless state.
[0059] [0059] For example, the spiro form of an oxazine is a colorless white dye; the conjugated system of the oxazine and another aromatic part of the molecule is separated by a spiro hybridizing carbon "spiro". After protonation of a part of the molecule, irradiation with UV light or the introduction of other types of such alteration, the connection between the spiro carbon and the oxazine stops, the ring opens, the spiro carbon reaches sp2 hybridization and becomes flat, the aromatic group rotates, aligns its n orbitals with the rest of the molecule and forms a conjugate system, with the ability to absorb photons of visible light, and, consequently, appears colored.
[0060] [0060] The leuco dyes that can be employed can be selected from a variety of dyes, including, for example, phthalide leuk dyes, leuko triarylmethane dyes, and fluoran leuk dyes. Examples may include (1) triarylmethane-based dyes, for example, 3,3-bis (p-dimethylaminophenyl) -6-dimethylaminophthalide, 3,3-bis (pdimethylaminophenyl) phthalide, 3- (p-dimethylaminophenyl) -3 - (1,2-dimethylindol-3-yl) phthalide, 3- (p-dimethylaminophenyl) -3- (2-methylindol-3-yl) phthalide, 3,3-bis (1,2-dimethylindol-3-yl ) -5-dimethylaminophthalide, 3,3-bis (1,2-dimethylindol-3-yl) -6-dimethylaminophthalide, 3,3-bis (9-ethylcarbazol-3-yl) -6-dimethylaminophthalide, 3,3- bis (2-phenylindol-3-yl) -6-dimethylaminophthalide, 3-p-dimethylaminophenyl-3- (1-methylpyrrol-3-yl) -6-dimethylaminophthalide, (2) diphenylmethane dyes, e.g. , 4,4'-bisdimethylaminobenzhydryl benzyl ester, Nhalophenilleucoauramine, N-2, 4,5-trichlorophenyl-leucoauramine, etc. (3) lactam-based dyes, e.g., rhodamine-B-anilinolactam, rhodamine- (pnitroanilino) lactam, rhodamine- (o-chloroanilino) lactam (4) fluorane-based dyes, for example 3- dimethylamino-7-methoxyfluorane, 3-diethylamino6-methoxyfluorane, 3-diethylamino-7-methoxyfluorane, 3-diethylamino-7-chlorofluorane, 3-diethylamino-6-methyl-7-chlorofluorane, 3-diethylamino-6,7-dimethylfluane, 3- (N-ethyl-p-toluidino) -7-methylfluorane, 3-diethylamino-7- (Nacetyl-N-methylamino) fluorane, fluorane, 3-diethylamino-7- (Nmethylamino) fluorane, 3-diethylamino-7- dibenzylaminofluorane, 3-diethylamino7- (N-methyl-N-benzylamino) fluorane, 3-diethylamino-7- (N-chloretoethyl-Nmethylane) fluorane, 3-diethylamino-7-N-diethylaminofluorane, 3- (N-ethyl-ptoluidino ) -6-methyl-7-phenylaminofluorane, 3- (N-ethyl-p-toluidino) -6-methyl-7- (ptoluidino) fluorane, 3-diethylamino-6-methyl-7-phenylaminofluorane, 3-diethylamino-6 -methyl-7- (p-toluidino) fluorane, 3-diethylamino-6-methyl-7-phenylaminofluorane, 3-dibutylamino-6-methyl-7-phenylaminofluorane, 3-di ethylamino-7- (2-carbomethoxyphenylamino) fluorane, 3- (N-cyclohexyl-Nmethylamino) -6-methyl-7-phenylaminofluorane, 3-pyrrolidine-6-methyl-7-phenylaminofluorane, 3-piperidine-6-methyl-7 -phenylaminofluorane, 3-diethylamino-6-methyl-7- (2,4-dimethylamino) fluorane, 3-diethylamino-7- (o-chlorophenylamino) fluorane, 3-diethylamino-7- (chlorophenylamino) fluorane, 3-dibutylamino- 7- (o-chlorophenylamino) fluorane, 3-pyrrolidine-6-methyl-7- (p-butylphenylamino) fluorane, 3- (N-methyl-N-namylamino) -6-methyl-7-phenylaminofluorane, 3- (N -ethyl-Nn-amylamino) -6-methyl7-phenylaminofluorane, 3- (N-ethyl, N-isoamylamino) -6-methyl-7-phenylaminofluorane, 3- (N-methyl-Nn-hexylamino) -6-methyl- 7- phenylaminofluorane, 3- (N-ethyl-Nn-hexylamino) -6-methyl-7-phenylaminofluorane, 3- (N-ethyl-N-B-ethylhexylamino) -6-methyl-7-phenylaminofluorane, etc. The basic dyes useful in this invention are not limited to those exemplified above, and at least two of them can be used in a mixture.
[0061] [0061] Alternatively, the visual indicator component of the multisensory indicator composition may be a color-changing dye, such as a dye / ink sensitive to employing one or more pH-altering dyes / chromogens to achieve a color-changing effect. desired color. The particular chromogens used in the pH sensitive dye-based embodiment are generally not essential, unless you want to correlate the pH indicator dye with the presence of a specific body fluid. For example, phthalin chromogens are a class of suitable pH sensitive dyes that can be used in the present disclosure. Phenol red (i.e., phenolsulfonaphthalene), for example, exhibits a transition from yellow to red over the pH range of 6.6 to 8.0. Above a pH of about 8.1, the phenol red turns a bright pink (fuchsia) color. The phenol red derivatives may also be suitable for use in the present disclosure, such as those substituted with chlorine, bromine, methyl, sodium carboxylate, carboxylic acid, hydroxyl functional groups and amines. Examples of substitute compounds for phenol red include, for example, Metacresol Purple (meta-cresolsulfonephthalate), Cresol Red (orthosesolphonephthalate), Pyrocatechol Violet (pyrocatecholsulfonephthalein), Chlorophenol Red (3 ', 3' '- dichlorophenolsulfone ), Xylenol Blue (the sodium salt of paraxylenolsulfonephthalein), Xylenol Orange, Mordante Blue 3 (CI 43820), 3,4,5,6- tetrabromophenolsulfonophthalein, Bromoxyenol Blue, Bromophenol Blue (3 ', 3' ', 5', 5 '' - tetrabromophenolsulfonophthalein), Bromochlorophenol Blue (the sodium salt of dibromo-5 '5' '- dichlorophenolsulfonephthalein), bromocresol purple (5', 5 '' - dibromo-orthocresolsulfonephthalein), and Green of bromocresol (3 ', 3' ', 5', 5 '' - tetrabromo-orthocresolsulfonephthalein). For example, bromocresol green exhibits a transition from yellow to blue over a pH range of about 4 to about 6; Bromothymol Blue exhibits a transition from yellow to blue over a pH range of about 6.0 to 7.6; Bromophenol Blue exhibits a transition from yellow to violet over a pH range of about 3.0 to 4.6; and Bromocresol Purple exhibits a transition from yellow to violet over a pH of about 5.2 to 6.8.
[0062] [0062] Anthraquinones are another appropriate class of pH sensitive dyes for use in the present disclosure. They have the following general structure:
[0063] [0063] The numbers 1-8 shown in the general formula represent a location on the fused ring structure in which the substitution of a functional group can occur. Some examples of such functional groups, which can be substituted on the fused ring structure include halogen groups (for example, chlorine or bromine groups), desulfonyl groups (for example, sulfonic acid salts), alkyl groups, benzyl groups, amino groups (e.g., primary, secondary, tertiary or quaternary amines), carboxy groups, cyano groups, hydroxyl groups, phosphorus groups, etc. Functional groups that result in an ionization capacity are often referred to as "chromophores." Replacing the ring structure with a chromophore causes a change in the absorption wavelength of the compound. Thus, depending on the type of chromophore (for example, hydroxyl, carboxyl, amino, etc.) and the degree of substitution, a wide variety of quinones can be formed with varying colors and intensities. Other functional groups, such as sulfonic acids, can also be used to generate certain types of compounds (for example, water-soluble anthraquinones of higher molecular weight).
[0064] [0064] Some suitable anthraquinones that can be used in this description, as classified by their "CE" numbers, include Acid Black 48, Acid Blue 25 (D&C Green No. 5), Acid Blue 40, Acid Blue 41, Acid Blue 45, Acid Blue 80, Acid Blue 129, Acid Green 25, Acid Green 27, Acid Green 41, Acid Violet 43, Mordant Red 11 (Alizarin), Mordant Black 13 (Alizarin Blue Black B), Mordant Red 3 (Alizarin Red S ), Mordant Violet 5 (Alizarin Violet 3R), Alizarin Complexone, Natural Red 4 (carminic acid), Disperse Blue 1, Disperse Blue 3, Disperse Blue 14, Natural Red 16 (Purpurin), Natural Red 8, Reactive Blue 2 (Procion Blue HB), Reactive Blue 19 (Remazol Brilliant Blue R); Alizarin, Alizarin Yellow R, Alizarin Yellow GG, Alizarin S, Nuclear Fast Red, Quinalizarin, Emodin, amino-4-hydroxyanthraquinone, and so on. For example, carminic acid exhibits a first transition from orange to red over a pH range of about 3.0 to 5.5 and a second transition from red to violet over a pH range of about 5 , 5 to 7.0.
[0065] [0065] Yet another appropriate class of pH sensitive dyes that can be used are aromatic azo compounds that have the general structure: X-R1 — N = N-R2-Y Where, R1 is an aromatic group; R2 is selected from the group consisting of aliphatic and aromatic groups, and X and Y are independently selected from the group consisting of hydrogen, halides, -NO2, -NH2, aryl groups, alkyl groups, alkoxy groups , sulfonate groups, -SO3H, -OH, -COH, -COOH, halides, etc. Also suitable are azo derivatives, such as azo compounds (X-R1-N = NO-R2-Y) or hydrazo compounds (X-R1-NH-NH-R2-Y). Particular examples of such azo compounds (or derivatives) include methyl violet, methyl yellow, methyl orange, methyl red and methyl green. For example, methyl yellow undergoes a transition from red to yellow with a pH range of about 2.9 to 4.0, methyl orange undergoes a transition from red to yellow to a pH range of about 3 , 1 to 4.4, and methyl red undergoes a transition from red to yellow at a pH range of about 4.2 to 6.3. Still other suitable pH-sensitive chromogens that can be employed include Congo Red, Litmus Blue (azolithmine), Methylene Blue, Neutral Red, Acid Fuchsin, Indigo Carmine, Bright Green, Picric Acid, Methanyl Yellow, Purple M- Cresol, Quinaldine red, Tropaeoline OO, 2,6-dinitrophenol, phloxin B, 2,4-dinitrophenol, 4-dimethylaminoazobenzene, 2,5-dinitrophenol, 1-naphthyl red, chlorophenol red, hematoxylin, 4-nitrophenol, Yellow Nitrazine and 3-nitrophenol.
[0066] [0066] Alternatively, thermochromic dyes can be used as they are sensitive to changes in temperature in the absorbent article and exhibit a color change effect, caused by different temperatures from the aqueous medium deposited on the article. Such a change in temperature can be caused by the soiling of the article with urine, menstruation or feces. Thermochromic dyes or dyestuffs for use in the composition include polymers, such as polythiophene, and liquid thermochromic crystalline materials. These dyes / coloring agent materials are available from a variety of sources, including HW Sands Corporation.
[0067] [0067] Alternatively, polarity sensitive dyes for the effect of color change can be used in the composition. Examples of polarity sensitive dyes include REICHARDT dye, 1-ethyl-4-methoxycarbonylpridinium iodide, 2,6-diphenyl-4- (2,4,6-triphenylpyridinium) phenolate (1), 4 [(1-methyl-4- (1H) -pyridinylidena) - ethylidene] -2,5-cyclohexadiene-1-one (2), and 4- [4- (dimethylamino) styryl] -1-methylpyridinium iodide.
[0068] [0068] Dyes with color change, desirably dyes with pH change, can be present in the composition between about 0.01% by weight to about 10% by weight. Generally, the amount of dye with a pH change can range from about 0.05 or 0.1% by weight to about 4 or 5% by weight, or 6 or 7% by weight; desirably, the range is between about 0.5 and 1% by weight to about 2.5, 3 or 5% by weight, inclusive. If present, the amount of thermochromic dye or polarity sensitive dye present in the composition would be similar to the predicted values for leuco dyes or pH dyes.
[0069] [0069] As previously noted with olfactory indicators, one or more multisensory compositions with different visual indicators can be placed in different locations within the absorbent article. Each can be placed at different distances from a peripheral side edge of the absorbent article or an inner layer of the absorbent article.
[0070] [0070] Depending on the type of dye used in the multisensory indicator coating composition sensitive to the aqueous medium, several other chemicals can be used in the composition. For example, as has been observed for compositions with leuco dyes, the inclusion of developers is desirable. Surfactants and binders are also desirable components of the composition. Examples of suitable developers include bisphenol A, zinc chloride, zinc salicylate and phenol resins. Other examples of color development materials to be used in conjunction with leuco dyes may include: 4-tert-butylphenol, anaftol, B-naphthol, 4-acetylphenol, 4-tert-octylphenol, 4,4'-sec-butylidenophenol, 4-phenylphenol, 4,4'-dihydroxydiphenylmethane, 4,4'-isopropylidene diphenol, hydroquinone, 4,4'-cyclohexylidene diphenol, 4,4-dihydroxy diphenylsulfide 4,4'-thiobis (6-tert-butyl-3- methylphenol), 4,4'-dihydroxydiphenyl sulfone, hydroquinone monobenzyl ether, 4-hydroxybenzophenone, 2,4-dihydroxybenzophenone, 2,4,4'-trihydroxybenzophenone, 2,2 ', 4,4'-tetrahydroxybenzophenone, dimethyl 4-hydroxiftalate , methyl 4-hydroxybenzoate, ethyl 4-hydroxybenzoate, propyl 4-hydroxybenzoate, sec-butyl 4-hydroxybenzoate, pentyl 4-hydroxybenzoate, phenyl 4-hydroxybenzoate, benzyl 4-hydroxybenzoate, tolyl 4-hydroxybenzoate, chlorophenyl 4-hydroxybenzoate, phenylpropyl -hydroxybenzoate, phenethyl 4-hydroxybenzoate, p-chlorobenzyl 4-hydroxybenzoate, p-methoxybenzyl 4-hydroxybenzoate, phenol resins of the tip novolak, phenol polymers and similar phenol compounds. If present, the amount of color developers in the composition of the multisensory indicator is about 1 to 25% by weight, alternatively from about 1 to about 10% by weight. such as leuco dyes, color developers generally exhibit good solubility in organic solvents.
[0071] [0071] If dyes that change color with pH change indicator are used as the basis for a visual moisture indicator that changes color in the multisensory indicator composition, such composition desirably includes a pH regulator such that the pH is maintained at a certain level before exposure to water-based body fluids. After exposure to such dirt by body fluids, the pH of the substrate with the coating will change, thus triggering the color change effect. The pH regulator is a molecule or composition that can be used to control the pH of the color-changing composition. The pH regulator can be an acid, a base or a combination of both, as would be found with a buffer composition. The pH regulator is selected in conjunction with the dye option to be used in the color changing composition. For example, if the color-changing composition includes a dye that has a color transition point that occurs at a pH below 5.5, the selected pH regulator is desirably an acid to make the pH of the changing composition acidic. by heart. If the color-changing composition includes a dye that transitions at a pH greater than 9.5, the selected pH regulator is desirably a basis for making the pH of the color-changing composition basic.
[0072] [0072] Examples of suitable acid pH regulators include organic acids, inorganic acids and polymeric acids; more specifically, examples of such acids include organic acids, glycolic acid, citric acid, lactic acid, ascorbic acid, oxalic acid, maleic acid, tartaric acid, salicylic acid, palmitic acid and stearic acid. Other examples of organic acids include polyacrylic acids, polymethacrylic acids and copolymers containing acrylic acids, methacrylic acids or both acrylic acids and methacrylic acids. Examples of suitable basic pH regulators include organic bases, inorganic bases and polymeric bases; more specifically, examples include sodium hydroxide, sodium carbonate, sodium bicarbonate, sodium borate, potassium hydroxide, polymeric amines, dendrimeric amine and 1,3-pentanediamine.
[0073] [0073] The pH regulators are desirably present between about 1 and 30% by weight of the composition, alternatively between about 5 and 20% by weight. Other examples of pH regulators can be found in US Publication 2011/0015599 for Song et al, which is incorporated herein in its entirety for reference purposes.
[0074] [0074] The solution of the homogeneous coating composition may contain a binder so that the solution can be used as an ink suitable for printing and that it can be air-dried without heating. Binders serve specifically to make the multisensory aqueous-sensitive indicator composition more suitable for printing. The binders also serve to protect the dye molecules responsible for the effect of color change and the betaine ester molecules responsible for the alteration of smell, from the ambient humidity experienced as humidity. In addition, the binders create a strong adhesion between the composition molecules and the support or substrate on which the multisensory indicator composition will be arranged. Suitable binders include, but are not limited to, compositions consisting of soluble polymeric resins, mainly organic, such as modified celluloses, polyesters and polyamides. Varnishes based on organic solvents are also suitable bonding compositions. Desirable specific binders include nitrocellulose, cellulose acetate-propionate, cellulose acetate butyrate and other water-insoluble binders. Other binders include hydroxyethyl cellulose; methyl cellulose; ethyl cellulose; carboxymethyl cellulose; polymers soluble in an organic solvent, such as polyvinyl butyral, polyvinyl acetate, vinyl acetate-vinyl chloride copolymer, acrylic resin, styrene resin and polyester resin. Binders can be present from about 10, 20, 30 or 70% by weight.
[0075] [0075] Based on the substrate or surface on which the multisensory indicator composition, sensitive to the aqueous medium will be deposited, the indicator composition may require the addition of other ingredients to immobilize or cause the dye (coloring agent), or other components to adhere more firmly to the substrate. The multisensory indicator composition may also contain wettability-enhancing agents, such as surfactants and or water-miscible or hydrophilic polymers. In addition, the composition may also contain other additives to adjust viscosity, surface tension, or other physical and chemical properties. Alternatively, the substrates can be treated with different materials to modify their surface properties before depositing the multisensory indicator composition, to improve the adhesion of the composition. The wettability-enhancing agent can be a single surfactant or a mixture of surfactants. Surfactants can be non-ionic, neutral or ionic. Ionic surfactants can be positively or negatively charged. Examples of nonionic surfactants include poly alkyl (ethylene oxide), such as copolymers of poly (ethylene oxide) and poly (propylene oxide) (commercially called Poloxamers or poloxamines), alkyl polyglucosides, such as octylglucoside and decyl maltosides, fatty alcohols such as cetyl alcohol, oleyl alcohol, cocoamide MEA and cocamide DEA. Examples of ionic surfactants include anionic (for example, based on sulfate, sulfonate or carboxylate anions), such as s (SDS) surfactants, ammonia lauryl sulfate and other alkyl sulfate salts, sodium laureth sulfate, also known as sodium lauryl ether sulfate (SLES), alkyl benzene sulfonate, soaps or fatty acids; and cationic surfactants (for example, based on quaternary ammonium cadmium), such as cetyl trimethylammonium bromide (CTAB) or trimethyl hexadecyl ammonium bromide and other alkyl trimethylammonium salts, Cetylpyridinium chloride (CPC), polyethoxylated tallow amine POEA), benzalkonium chloride (BAC), benzethonium chloride (BZT); or zwitterionic (amphoteric) surfactants, such as Betaine dodecyl, Dimethylamine oxide dodecyl, Betaine cocamidopropyl, Coco-anphoglycinate. Alternatively, the wettability-enhancing agents can also be hydrophilic molecules. Hydrophilic molecules can also be polymers, such as polyethylene glycol and its copolymers. Desirable surfactants include different classes, depending on the type of indicator system. For example, for paints that exhibit color, no surfactant is desirable. For paints whose colors fade, nonionic or neutral surfactants are desirable. For paints based on pH indicator dyes, charged surfactants are desirable, such as cationic surfactants. Desirably, if such surfactants are present in the composition, they are present in an amount between about 0.1 to 10% by weight. Alternatively, if such surfactants are present in the composition in an amount between about 0.1 to 10% by weight. Alternatively, if such surfactants are present in an amount between about 1 and 5% by weight. In an embodiment of the ink compositions based on pH indicator dyes, such surfactants are desirably present in an amount comprised between 0.1 and 10% by weight, alternatively between 0.5 and 5% by weight.
[0076] [0076] Additional coating components that can be used in the composition include desensitizers, especially for use with leuco dyes. Desirably, if used, the desensitizer of the present disclosure is of low molecular weight. Most desirably, the desensitizer is a zwitterionic molecule having a molecular weight of about 100 to about 800, and a high solubility in water and organic solvents. A desensitizer is betaine. It may also be desirable to use a zwitterionic molecule having a molecular weight of about 100 to about 500; or, alternatively, about 200 to about 400. Suitable types of betaine include betaine C poly sugar, betaine ester-menthol and betaine hydrochloride. Other zwitterionic molecules considered include 2- (methacryloyloxy) ethyl 3-sulfopropyl) ammonium hydroxide. If present, the amount of desensitizers desirably present from about 1% by weight to about 30% by weight, alternatively from about 1% by weight to about 15% by weight. In yet another alternative embodiment, such desensitizers are desirably present from about 1% by weight to about 25% by weight. In yet another alternative embodiment, such desensitizers are desirably present from about 1% by weight to about 5% by weight. In yet another alternative embodiment, such desensitizers are desirably present from about 5% by weight to about 10% by weight, alternatively between about 5 and 15% by weight, alternatively, from about 5 and 25% by weight.
[0077] The coating composition triggered by the aqueous medium of the invention can be applied to an absorbent article, or layer within an absorbent article, by any number of known applications or printing techniques. For example, the coating composition of the present invention can be deposited on a substrate by various methods of deposition or surface printing, such as flexographic printing, gravure roller printing, stamping, screen printing, spraying techniques, " dip and squeeze "and digital printing methods. In addition, the composition can be applied in the molten form and left to solidify on the treated substrate.
[0078] [0078] The placement of multisensory coatings sensitive to the aqueous medium can be on any number of substrates. The substrate sheets can, for example, include woven or non-woven sheets. Such sheets may include synthetic or natural fibrous materials and combinations thereof, such as, for example, materials in the form of spunbond and meltblown blankets, carded blanket or airlaid materials, cellulosic, wool or synthetic yarns. Such sheets may further include dry or wet cellulose-based sheets of paper or tissue. In addition, such substrates may include film sheets, film laminates and fibrous layers, or laminates of multiple fibrous layers. In addition, such substrates may include foams, such as open or closed cell foams. Such substrates / sheets can be layered within absorbent articles, or can themselves serve as the absorbent article, such as a towel, fabric or handkerchief.
[0079] [0079] The placement of a coating composition sensitive to the aqueous medium in an absorbent article can be along all the longitudinal or transverse or lateral dimensions (width) of a complete article, or a layer of an article, or alternatively, can be limited to certain regions within the article or layer (s) in the article. For example, such a chemical can be placed in a location specifically designed to contact water-based waste, such as in a highly likely "dirt area" or in the central crotch region in an article or layer. In another example, the coating composition can be placed adjacent to a peripheral side edge of an absorbent article in one or more layers, to serve as an indicator of impending leakage of waste from an absorbent article. For example, in one embodiment, that coating composition is attached to the absorbent article, or at least to a layer in the absorbent article, along a longitudinally directed lateral peripheral edge of the article, or layer, respectively. Desirably, such coating chemistry is placed adjacent to the peripheral side edge of the absorbent article, or adjacent to a peripheral side edge of the layer within an absorbent article, as a capacity indicator. Such coatings and coated layers can be used in any number of locations and components within the final product (absorbent article) that may come into contact with the aqueous medium, including, but not limited to, the upper layer, the back layer (inner face) or absorbent core layer. The coverings can be positioned in several separate locations in an individual layer, or in several layers, such as in an insulting central deposition zone or along the peripheral edges of the layer / article. Other positioned inner layers can also be coated with the coating composition. In an alternative embodiment, if a relatively hydrophobic betaine ester is selected for the composition (or one having relatively hydrophobic R3-R5 groups), it may be desirable to limit the placement of the coating formulation to certain locations on an absorbent article that does not. would directly affect the absorption pathways of an article, for example on an inner surface of a back layer (as opposed to an upper layer or central absorbent layer), or side areas of an upper layer, central absorbent layer or the other layer located inside.
[0080] [0080] When a fragrance is detected by a caregiver or user of the absorbent article, even though a visual inspection may not be possible immediately, the caregiver or user would recognize (by the scented odor) that moisture has been deposited in a location adjacent to the peripheral side article or layer of an article or layer, or propagated to a location adjacent to the peripheral side border of the article or layer within the article.
[0081] [0081] For the purposes of this application, the term "peripheral edge" refers to an outer edge of a layer or article. For the purposes of this application, the term "adjacent", will mean in one embodiment, between about 0 and 5 cm from a peripheral side edge of an absorbent article, or layer within an absorbent article, alternatively between about 0, 1 cm and 5 cm, from a peripheral lateral edge. In another alternative embodiment, the term adjacent will mean between about 0 and 3 cm from a peripheral side edge of an absorbent article, or layer within an absorbent article, alternatively between about 0.1 cm and 3 cm from an absorbent article. peripheral lateral border. In another alternative embodiment, the term adjacent will mean between about 0 and 2 cm from a peripheral side edge of an absorbent article, or layer within an absorbent article, alternatively between about 0.1 cm and 2 cm from an absorbent article. peripheral lateral border. The peripheral side edge of the article or layer can be a longitudinally directed side edge or a front or rear side edge. It should be noted that the placement of the coating on the absorbent article or a layer within the absorbent article can, in one embodiment, be adjacent to any peripheral side edge of the article or layer within the article, in order to serve as an indicator desirable capacity. Alternatively, such a coating can be placed only along the peripheral side edges of the article or layer at discrete localized points that have a tendency to leak, such as the wing or flap areas (as in the case of female absorbent articles), or in the openings of the legs, lateral areas of the groin, or areas of the opening at the waist (as in the case of diapers and incontinence products). Alternatively, such a coating composition can be placed in locations not adjacent to a peripheral side edge of the article or layer within an article, so as to provide an immediate indication of dirt (by the release of the fragrance) and odor masking functionality. This can be especially beneficial for the application of a product where the consumer is prone to extreme irritation in the event of prolonged exposure to liquid moisture, or for a consumer who is particularly interested in maintaining the discretion and security that their absorbent products do not. are leaking and causing stains. The coating with the color-changing dye and betaine ester can be applied as a monochromatic, bichromatic, or multiple color scheme, or printed / applied in various shapes and sizes, pattern graphics or alphanumeric symbols and / or words (such as tags or messages), or their combinations. Therefore, the release of the volatile fragrance can be used to mask an unpleasant odor, an aromatic hint that dirt has occurred or that the article's capacity has been reached or is about to be reached (and that leakage may be imminent).
[0082] [0082] In an alternative embodiment, the indicator coating of the present invention can be applied / affixed in several separate locations along the dimensions of the article, each with different olfactory indicators or visual indicators in the composition, such that different aromas or color changes released, or seen by the consumer, would present a graduated warning system of impending leakage, each smell or color indicating a different distance from the peripheral lateral edge of the article or layer. By providing both a graduated visual and aromatic tip to a consumer or caregiver, leakage of an absorbent article can be prevented. It is desirable in one embodiment, that such a multisensory coating composition triggered by aqueous medium can be initially in the form of a homogeneous liquid (solution), an emulsion, an ink, a suspension or a hot melt and then deposited on a solid substrate, such as for example a film, woven or non-woven sheet or water absorbent central layer sheet material.
[0083] [0083] In a desirable embodiment of the aqueous-sensitive coating composition of the invention, the coating composition includes a betaine ester or betaine ester derivative with functional active, and at least one triggerable indicator of aqueous medium additional, to provide a visual indication of an aqueous liquid with such a visual indicator being a pH indicator dye that changes color with a pH regulator. In yet another embodiment of the coating composition, the composition can include a betaine ester or betaine ester derivative with functional active, a color-changing pH indicator dye, a pH regulator such as an acid or a base, a surfactant, and a binder. In addition, as noted above, the coating composition desirably includes a solvent.
[0084] [0084] In yet another alternative embodiment of the invention, such coated polymer film, woven or non-woven sheets or laminates of these sheets, are used in at least one part / component of a disposable absorbent article. Such a coated material can, for example, be used as a coated component of the lower layer, upper layer or absorbent central layer of a disposable absorbent article. In yet another alternative embodiment, such a coated material can be employed as a component of an absorbent cleaning sheet or sheet. When using such coated materials in an absorbent article, such a composition can be used to detect moisture in an aqueous medium, or the dirt of an article from urine, vaginal secretions, mucous, menstruation, feces or a domestic spill. In addition, this composition can, at the same time, also mask odors and provide aesthetic characteristics of an absorbent article. The formulations of the above coatings are demonstrated through the following series of examples. Examples:
[0085] [0085] The following components were mixed together to form multisensory moisture indicator coating compositions for the purpose of demonstrating the effectiveness of using a betaine ester and dye / ink in accordance with the present disclosure. Example 1 (functional asset of the betaine ester)
[0086] [0086] A butanone solution was prepared containing 20% butyrate cellulose acetate (binder), 1% crystal violet lactone (white dye), 12% zinc salicylate (developer), 10% BASF Pluronic P 85 (wetting agent), 5% decadnoic sodium sulfate (surfactant) and 1% eugenol (not betaine ester). The solution was brushed on a polypropylene outer film and air dried. The essence of eugenol was readily detected continuously by a human nose when approaching the film. The essence of eugenol was detected by normal inhalation through the human nose (from the same distance) for about four days, under environmental conditions. After four days, little eugenol odor was detected by a human nose, even after wetting. An increased smell of eugenol was detected when a freshly prepared film sample (no more than 24 hours) was wetted by water. At the same time, the color of the film changed from blue to colorless when moistened. Example 2
[0087] [0087] A butanone solution was prepared containing 20% butyrate cellulose acetate, 1% crystal violet lactone, 12% zinc salicylate, 10% BASF Pluronic P 85, 5% decadno sodium sulfate and 1 % eugenol betaine ester. The solution was brushed on a polypropylene outer film and air dried. No smell of eugenol was detected by the human nose when approaching the film. When moistened, the smell of eugenol was readily detected by a human nose. The sample remained in environmental conditions for two months; the smell of eugenol was readily detected by a human nose when wetted by water. At the same time, the color of the film changed from blue to colorless when moistened. Example 3 (Example using a color-changing pH indicator dye).
[0088] [0088] A solution was prepared by dissolving 10 mg of bromocresol green (pH dye), citric acid 100 mg (pH regulator), polyacrylic acid 50 mg (pH regulator), 30 mg benzethene chloride (agent wetting enhancer) and 300 ml of nitrocellulose-based varnish (binder) from SunChemical Co. in 500 microliters of ethanol. 20 mg of menthol betaine ester dissolved in 100 microliters of ethanol was added to the solution and mixed well. The solution was brushed over a piece of polypropylene film to form a thin coating and air dried overnight. The menthol smell was detected when the coating was wetted with water. The color of the coating changes from yellow to blue.
[0089] [0089] A moisture indicator containing the multisensory coating composition to detect the presence of an aqueous-based liquid that has penetrated the absorbent article, is desirably immobilized or printed on one or more layers of an absorbent article. Such a moisture-indicating coating composition can be positioned, for example, on the top layer. In such a situation, the humidity indicator can be positioned on a user-facing surface of the upper layer, a surface facing the upper layer of clothing, or impregnated or within the upper layer itself. In an alternative embodiment, the moisture-indicating coating composition can be positioned along the longitudinally directed side edges of the top layer so as to not only provide a visual and aromatic indication of the soiling of the article, but also serve as a system alert to warn a user or caregiver of the impending leakage of the article as the aqueous medium seeps into the longitudinally directed side edges of such article. In another alternative embodiment, the moisture indicator can be positioned in discrete areas on the top layer, or, alternatively, along the entire surface of the top layer. In another embodiment, the humidity indicator can be positioned along the inner surface facing the user of the lower layer. As with the upper layer previously described, this indicator can be positioned in discrete areas or across the entire interior surface facing the user of the upper layer. In yet another alternative embodiment, the moisture indicator can be positioned on any outer surface of the central absorbent layer (either the user-facing surface or the garment-facing surface), or inside the layer (or absorbent core, if such an absorbent core includes multiple layers. In any case, it is desirable that the moisture indicating coating composition is visible to both the caregiver and the user. For example, when placing a composition on the inner surface facing the user of a lower layer, the indicator layer is desirably visible to the caregiver through the surface facing the garment of the lower layer of the article. When positioning the coating composition along the side edges of an article, in the same way, such composition is desirably visible to a user of articles such as feminine pads and liners.
[0090] [0090] In general, the multisensory coating composition triggered by the aqueous medium of the present disclosure can be incorporated into an absorbent article, in a variety of different configurations and orientations, as long as the coating composition is capable of receiving body fluids or waste aqueous (for example, urine and / or fecal material) and provide a signal to the user or care about the presence or absence of aqueous liquid. For example, the indication coating composition can be directly immobilized or printed on a part of the inner side of a lower film layer, an upper side facing the user of the upper layer, an inner surface of the upper layer, or the entire internal surface of the layer in communication with the liquid of the article. The coating composition can also be printed or immobilized on a piece of substrate to make a moisture indicator of different patterns that is sandwiched between the outer covering film and the absorbent core layer of the article, or between the other layers of an article pad.
[0091] [0091] The coating composition can be visible to the user or caregiver so that a simple, accurate and quick indication of humidity can be provided. Visibility can be achieved in several ways. For example, in some embodiments, the absorbent article may include a transparent or translucent part (e.g., window, film, etc.) that allows the coating composition to be easily viewed without removing the user's absorbent article and / or without disassembling the absorbent article. In other embodiments, the coating composition can extend through a hole or opening in the absorbent article for observation. In still other embodiments, the coating composition can simply be placed on a surface of the absorbent article for observation. Regardless of the particular way in which it is integrated, urine or other aqueous liquid can be discharged directly into a portion of the coating composition, or it can be discharged into a component of the absorbent article in which the coating composition has been integrated.
[0092] [0092] The moisture-indicating coating composition in the article desirably shows a strong color in its dry state. The strong color of the material of the indicating coating composition desirably changes to a second color when in contact with water or aqueous medium. Alternatively, the color becomes faint or disappears completely. The aqueous medium can be, for example, body fluids or other waste, such as mucus, menstrual flow, vaginal secretions, urine, feces or spills for domestic use.
[0093] [0093] Reference will now be made on the various ways of carrying out the disclosure, one or more examples of which are presented below. Each example is provided by way of explanation, not limiting disclosure. Indeed, it will be apparent to those skilled in the art that various modifications and variations can be made to the present disclosure without departing from the scope or spirit of the disclosure. For example, the features illustrated or described as part of one embodiment can be used in another embodiment, to obtain yet another embodiment.
[0094] [0094] In particular, a rear perspective view of a baby diaper 120 is illustrated in Figure 1. Diaper 120, may or may not be disposable. A chassis, as illustrated, can have an hourglass shape, in a detached configuration. However, other shapes can obviously be used, such as a generally rectangular shape, a T shape, or an I shape. The diaper can include a chassis made up of several components, including an outer cover or bottom layer, a lining of the side of the body or top layer, at least one aqueous liquid, the central absorbent layer, and an optional wave layer. It should be understood, however, that the other layers can also be used in exemplary embodiments of the present disclosure. Likewise, one or more of the layers can also be eliminated in certain exemplary embodiments of the present disclosure. By way of illustration only, a variety of materials and methods for constructing absorbent articles such as diaper 120 are disclosed in PCT patent application WO 00/37009 to Fletcher et al .; US patent 4,940,464 to Van Gompel et al .; US patent 5,766,389 to Brandon et al., And US patent 6,645,190 to Olson et al. which are hereby incorporated in their entirety for reference purposes.
[0095] [0095] Diaper 120 is shown in Fig. 1 in a partially tightened condition. The diaper 120 shown in Figs. 1 and 2 is also shown in Figs. 3 and 4 in an open and unfolded state. Specifically, Fig. 3 is a plan view showing the outside of diaper 120, while Fig. 4 illustrates an alternative embodiment on the inside of diaper 120. As shown in figs. 3 and 4, the diaper 120 defines a longitudinal direction 148 that extends from the front of the article when dressed to the rear of the article. Opposite the longitudinal direction 148 is the lateral (or transverse) direction 149.
[0096] [0096] Diaper 120 defines a pair of longitudinal end regions, also referred to herein as a front region 122 and a rear region 124, and a central region, also referred to here as groin region 126, extending longitudinally between and interconnecting the front and rear regions 122, 124. The diaper 120 also defines an inner surface 128 adapted in use (eg positioned in relation to the other components of article 120) facing the user, and an outer surface 130 opposite the surface internal. The front and rear regions 122, 124 are these parts of the diaper 120 that, when used, cover or completely or partially cover the waist or the central-lower part of the user's torso. The groin region 126 (central liquid deposition zone) is usually the part of the diaper 120 that, when used, is positioned between the user's legs and covers the lower part of the user's torso and groin. The absorbent article 120 has a pair of laterally opposite side edges 136 and a pair of longitudinally opposite waist edges, respectively designated with front waist edge 138 and rear waist edge 139. The illustrated diaper 120 includes a chassis 132, which aspect, it comprises the front region 122, the rear region 124 and the crotch region 126. With respect to Figs. 3-4, chassis 132 includes a lower layer facing clothing 140 and an upper layer facing user 142 (Figs. 1 and 4) that can be joined up to the lower layer 140 in an overlapping relationship with the aid of adhesives , ultrasonic binders, thermal binders or other conventional techniques.
[0097] [0097] Generally, the user-facing top layer 142 can be used to help isolate the user's skin from the liquids contained in the absorbent center bed 144. For example, the top layer 142 has a body-facing surface that is typically compatible, soft to the touch and does not irritate the user's skin. Typically, the top layer 142 is also often less hydrophilic than the central absorbent layer 144, so that its surface remains relatively dry for the user. As indicated above, the top layer 142 can be liquid permeable to allow the liquid to easily penetrate through its thickness. Exemplary top layer constructions that contain a nonwoven blanket are described in U.S. Patent Nos. 5,192,606 to Proxmire et al .; 5,702,377 to Collier, IV, et al .; 5,931,823 to Stokes, et al .; 6,060,638 to Paul, et al .; and 6,150,002 for Varona, as well as US Patent Application Publication No. 2004/0102750 to Jameson; 2005/0054255 for Morman, et al .; and 2005/0059941 to Baldwin, et al., all of which are incorporated herein in their entirety for reference purposes.
[0098] [0098] The bottom layer facing the garment 140 can generally be formed from a material that is substantially impermeable to liquids. For example, the bottom layer 140 may be formed from a thin film of plastic or other flexible liquid impermeable material, such as a non-woven or hydrophobic non-woven laminate material. In one embodiment, the bottom layer 140 is formed from a polyolefin (polyethylene) film with a thickness of about 0.01 millimeter to about 0.05 millimeter. The film may be impermeable to liquids, but permeable to gases and water vapor (ie "breathable"). This allows for the release of vapors from the absorbent core layer 144, but still prevents liquid exudates from passing through the bottom layer 140. If a more tissue-like sensation is desired, the bottom layer 140 can be formed from a polyolefin film laminated on a non-woven blanket. For example, a polyolefin film can be thermally laminated to a spunbond blanket of polypropylene fibers.
[0099] [0099] Referring to Fig. 4, the top layer 142 can be suitably joined to the bottom layer 140 along the perimeter of the chassis 132 to form a front waist seam 162 and a rear waist seam 164. As shown in Fig. 4, the top layer 142 can be suitably joined to the bottom layer 140 so as to form a pair of side seams 161 in the front region 122 and back region 124. The top layer 142 can generally be adapted, i.e., positioned with respect to to the other components of article 120, facing the user's skin when using absorbent article 120.
[0100] The chassis 132 can further include a structure of central absorbent layers, or central absorbent layer of aqueous liquid retention 144, particularly shown in fig. 4 disposed between the lower layer 140 and the upper layer 142 for the absorption of liquid body exudates exuded by the user. The diaper can also contain a substantially hydrophilic fabric wrap or extruded nonwoven wrap (not shown), which helps maintain the integrity of a fibrous or superabsorbent structure of the absorbent center layer 144. The fabric wrap is normally placed over the layer absorbent core 144 on at least the two main coating surfaces of the same, and is composed of an absorbent cellulosic material, such as crimped filler or a high moisture resistant fabric. The woven or non-woven wrapper can be configured to provide a drainage layer, which helps to quickly distribute the liquid over the absorbent fiber mass of the central absorbent layer 144. The wrapper material on one side of the absorbent fibrous mass can be joined to the wrapper located on the opposite side of the fibrous mass to effectively retain the central absorbent layer 144. In addition, the diaper 120 may also include a ventilation layer (not shown) that is positioned between the central absorbent layer 144 and the lower layer 140. When used, the ventilation layer can help insulate the lower layer 140 from the absorbent central layer 144, thereby reducing moisture in the lower layer 140. Examples of such ventilation layers may include a nonwoven blanket laminated to a permeable film. to air, as described in U.S. Patent No. 6,663,611 to Blaney, et al., which is incorporated herein in its entirety for reference purposes. reference
[0101] [00101] The diaper may also include a pair of retaining tabs 146 that are configured to provide a barrier and contain the lateral flow of body exudates. The containment flaps 146 can be located along the laterally opposite side edges of the upper layer 142 adjacent to the side edges of the central absorbent layer 144. The containment flaps 146 can project longitudinally along the entire length of the central absorbent layer 144 , or they can protrude only partially along the central absorbent layer 144. When the containment flaps 146 are shorter in length than the central absorbent layer 144, they can be selectively positioned anywhere along the side edges of the diaper 120 in a groin area. In one embodiment, the containment flaps 146 extend along the entire length of the central absorbent layer 144 to better contain the body exudates. Such containment flaps 146 are generally well known to those skilled in the art. For example, suitable constructions and containment flap arrangements 146 are described in U.S. Patent No. 4,704,116 to Enloe, which is incorporated herein in its entirety for reference purposes. As illustrated, a pair of retaining flaps 146 is shown attached to the top layer 142 to inhibit the lateral flow of body exudates. The elasticized containment flaps 146, as shown in Fig. 4, define a partially uncoupled edge that assumes a vertical configuration at least in the crotch region 126 of the diaper 120 to form a seal against the user's body. As shown, the containment flaps 146 extend longitudinally along the entire length of the chassis 132.
[0102] [00102] To improve the containment and / or absorption of body exudates, diaper 120 can also suitably include elastic members in the legs 158 (Fig. 4), as are known to those skilled in the art. The elastic members in the legs 158 can be operatively joined to the lower layer 140 and / or the upper layer 142 and positioned in the crotch region 126 of the absorbent article 120. The elastic members in the legs 158 can be made of any suitable elastic material. As is well known to those skilled in the art, competent elastic materials include sheets, threads or tapes of natural rubber, synthetic rubber or thermoplastic elastomeric polymers. The elastic materials can be stretched and glued to a substrate, glued and a substrate collected or glued to a substrate and then elasticized or shrunk, for example, with the application of heat, so that the forces of elastic retraction are transmitted to the substrate. In a particular aspect, for example, the elastic members in the legs 158 can include a plurality of multifilamentous spandex elastomeric yarns coalesced by extrudate drying, marketed under the trade name LYCRA.
[0103] [00103] In some respects, the absorbent article 120 may further include a wave control layer (not shown), which may optionally be located adjacent to the structure of the central absorbent layer 144 and joined to various components in article 120, such as structure of the central absorbent layer 144 or the body side lining 142, by methods known in the art, such as through the use of an adhesive. A wave control layer helps to slow down and diffuse waves or jets of liquid that can be quickly introduced into the article's absorbent structure. Desirably, the wave control layer can quickly and temporarily accept to retain the liquid, before releasing it to the storage or retaining parts of the absorbent core layer structure 144. Examples of suitable wave control layers are described in the Patent No. 5,486,166 to Bishop et al. and U.S. Patent No. 5,490,846, to Ellis et al. Other suitable wave control materials are described in U.S. Patent No. 5,820,973 to Dodge III et al. The full descriptions of these patents are hereby incorporated by reference.
[0104] [00104] As shown in Figs. 1-4, the absorbent article 120 further includes a pair of elastic side panels 134 which are coupled to the rear region of the chassis 132. As particularly shown in Figs. 1 and 2, side panels 134 can be stretched around a user's waist and / or hips in order to hold the part in place. As shown in Figs. 1 and 2, the elastic side panels (or ears) are coupled to the chassis 132 along a pair of opposing longitudinal edges 137. The side panels 134 can be coupled or connected to the chassis 132 using any suitable connection technique. For example, side panels 134 can be attached to the chassis by means of adhesives, ultrasonic connections, thermal connections or other conventional techniques. In an alternative aspect, the elastic side panels can also be formed integrally with the frame 132. For example, side panels 134 can include an extension of the upper layer 142, the lower layer 140, or both upper layers 142 and lower 140. In the aspects shown in the figures, the side panels 134 are connected to the rear region of the absorbent article 120 and extend across the front region of the article when fixing the article in place on a user. It should be understood, however, that the side panels 134 can alternatively be connected to the front region of the article 120 and extend to the rear region when the article is used.
[0105] [00105] With the absorbent article 120 in the tight position, as partially illustrated in Figs. 1 and 2, the elastic side panels 134 can be connected by a locking system 180 to define a three-dimensional diaper configuration that has a waist opening 150 and a pair of leg openings 152. The waist opening 150 of article 120 is defined by the edges of the waist 138 and 139 that surround the user's waist.
[0106] [00106] In the aspects shown in the figures, the side panels are releasably attachable to the front region 122 of article 120 by the closing system. It should be understood, however, that in other respects, the side panels 134 can be permanently attached to the chassis 132 at each end. The side panels 134 can be permanently connected together, for example, when forming training pants.
[0107] [00107] The elastic side panels 134 each have a longitudinal outer edge 168, an end edge of the leg 170 disposed towards the longitudinal center of the diaper 120, and waist end edges 172 disposed towards a longitudinal end of the absorbent article. The end leg edges 170 of absorbent article 120 can be suitably curved and / or arranged at an angle relative to the lateral direction 149 to provide a better fit around the user's legs. However, it is understood that only one of the end edges of leg 170 can be curved or angled, so that the end edge of the leg of the rear region 124, or alternatively, none of the end edges of leg can be curved or arranged in angle without departing from the scope of the present invention. As shown in Fig. 4, the outer edges 168 are generally parallel to the longitudinal direction 148 while the end edges of the waist 172 are generally parallel to the lateral axis 149. It is to be understood, however, that in other respects, the edges outer edges 168 and / or the edges of the waist 172 may be slanted or curved as desired. Ultimately, side panels 134 are generally aligned with a waist region 190 of the chassis.
[0108] [00108] The fastening system 180 may include first laterally opposite fastening components 182 adapted for re-fastening to the corresponding second fastening components 184. In the aspect shown in the figures, the first fastening component 182 is located on the elastic side panels 134, while the second fastener 184 is located in the front region 122 of the chassis 132. In one aspect, a front or outer surface of each of the fasteners 182, 184 includes a plurality of engagement or complementary elements. The engagement elements of the first fasteners 182 are adapted to engage and disengage repeatedly with the corresponding engagement elements of the second fasteners 184 to detachably fix the article 120 in its three-dimensional configuration.
[0109] [00109] The fastening components 182, 184 can be any reusable fastening elements suitable for absorbent articles, such as adhesive fasteners, cohesive fasteners, mechanical fasteners or the like. In particular aspects, the fastening components include mechanical fastening elements for improved performance. Suitable mechanical fastening elements can be provided by geometric shaped locking materials, such as hooks, loops, bulbs, mushrooms, arrows, rod balls, male and female coupling components, buckles, clasps or the like.
[0110] [00110] In the illustrated aspect, the first fasteners 182 include hook fasteners and the second fasteners 184 include complementary loop fasteners. Alternatively, the first fasteners 182 include hook fasteners and the second fasteners 184 can include complementary hook fasteners. In another aspect, the fasteners 182, 184 can interconnect similar surface fasteners, or adhesive or cohesive fasteners, such as an adhesive fastener and a receptive adhesive landing zone or material; or the like. Other such fasteners 182 may be a combination of hook and loop elements and adhesive elements. One skilled in the art will recognize that the shape, density and polymeric composition of the hooks and loops can be selected to obtain the desired level of coupling between the fastening components 182, 184. Suitable fastening systems are also described in the Order for PCT patent previously incorporated WO 00/37009, to Fletcher et al. and U.S. Patent 6,645,190 to Olson et al.
[0111] [00111] In the aspect shown in the figures, the fastening components 182 are connected to the side panels 134 along the edges 168. In this aspect, the fastening components 182 are not elastic or extensible. In other respects, however, the fasteners can be integral with the side panels 134. For example, the fasteners can be directly coupled to the side panels 134 on a surface of the panel.
[0112] [00112] In addition, the possibility of having elastic side panels, absorbent article 120 may include several elastic waist elements to provide elasticity around the waist opening. For example, as shown in the figures, the absorbent article 120 may include a front elastic waist member 154 and / or a rear waist elastic member 156.
[0113] [00113] The various regions and / or components of diaper 120 can be assembled together, using any known fixing mechanism, such as adhesive, ultrasonic, thermal connections, etc. Suitable adhesives can include, for example, hot melt adhesives, pressure sensitive adhesives, and so on. When used, the adhesive can be applied as a uniform layer, a patterned layer, a spray pattern, or any of separate lines, swirls or dots. In the illustrated embodiment, for example, the bottom layer 140 and the top layer 142 are mounted together and the absorbent center layer 144 using an adhesive. Alternatively, the absorbent center layer 144 can be joined to the bottom layer 140 using conventional fasteners, such as buttons, hook and loop fasteners, adhesive tape fasteners, and so on. Likewise, other diaper components, such as elastic leg members, waist and fasteners, can also be mounted on diaper 120 using any fastening mechanism.
[0114] [00114] As shown in Figs. 1-3, the multisensory moisture indicators of the coating compositions of the invention 200, 202 are affixed to the diaper 120 inside the surface (the user-facing surface) of the bottom layer 140, between the absorbent center layer 144 and the bottom layer 140, along the longitudinal direction of the central crotch region 148 of the article. Such longitudinally directed strips of the coating composition terminate at the horizontal (laterally directed) parts 204 and 206, such that if the absorbent article is being used, such a moisture indicator can be seen in the region of the waist of the worn diaper, as such diaper is used, and assuming this dirt has spread to the waist area. In addition, if the product is dirty, this indicator will be seen along multiple directions. As can be seen in Fig. 4, which illustrates an alternative embodiment of the diaper in Fig. 1, such humidity indicators 200, 202 may alternatively consist of discontinuous strokes, instead of continuous lines running from the front to the rear of the diaper 120. In yet another alternative embodiment, these indicators can be attached to the inner surface of the lower layer, adjacent to the peripheral side edges longitudinally directed near the leg openings, or adjacent to the peripheral side edges, close to the waist opening. In particular, these indicators can be attached adjacent to the opposite side edges 136 and / or the pair of longitudinally opposed waist edges, respectively designated 138 and 139. In such an example, if moisture is deposited or migrates to these areas, an aroma will be released indicating an impending leak. It should be recognized that, in relation to the diaper embodiment 120, shown in Figs. 1-4, such a coating composition may alternatively be positioned adjacent to the peripheral side edges of one or more upper layers, the absorbent center layer, or any other inner layer of the diaper (on user-facing surfaces or surfaces facing clothing, or multiple surfaces). The coating composition can also be placed on or within multiple layers.
[0115] [00115] As can be seen in Figs. 5 and 6, which illustrate an alternative embodiment of an absorbent article with multisensory moisture indicators including the composition of the invention, a female sanitary pad 250 is illustrated. As can be seen in the exploded perspective view of Figure 5, the female sanitary napkin 250 includes an upper layer 310 with an embossed design in the form of arcs 316 and a runway design, an absorbent central layer 340 with an embossed design in the form of zigzags or waves of 342, and a bottom layer 350. The top layer 310 includes a top surface facing the user 312 and a bottom surface facing the clothing 314. The sealing area 313 seals the top layer 310 with the bottom layer 350 The top layer 310 includes the front and rear 300 having peripheral side edges, and longitudinally directed peripheral side edges 311. The coating composition of the invention is affixed in an embodiment to the inner surface facing the garment 314 of the top layer 310 shown in lines 400, adjacent to the longitudinally directed peripheral side edges 311 of the upper layer 310. Alternatively, such a composition coating material could be easily affixed in similar positions along the surface of the top layer 310 facing the user 312. In addition, the coating composition of the invention is optionally affixed to the garment facing surface of the upper layer 314, in adjacent arcs 410 to the peripheral front and rear end edges 300 of the top layer 310.
[0116] [00116] As can be seen along the bottom layer 350 of fig. 5, the additional moisture indicators 400, 410 of the composition of the invention are also optionally positioned along the surface of the lower layer 350 facing the user 354, adjacent to the peripheral side edges of the longitudinally directed lower layer 351. The lower layer 350 includes a inner surface facing the user 354 and a surface facing the clothing 352. For the purposes of a feminine hygiene absorbent article 250, it may be desirable, in one embodiment, that the indicator composition is not visible through the surface of the layer bottom 352 facing clothing, to prevent it from being inadvertently seen through a user’s underwear.
[0117] [00117] As seen in Fig. 6, in an exploded cross-sectional view of the female sanitary pad 250 of Fig. 5, taken along lines 6-6, the moisture indicators with the coating composition of the invention 400 are affixed inside absorber 250 adjacent to the longitudinal peripheral side edges 402 of the absorber. These coating compositions of the invention are positioned adjacent to the longitudinally directed peripheral side edges 311, 351, separated from the longitudinally directed peripheral side edges by a distance "D", which is, desirably, in an embodiment, less than or equal to 5 cm alternatively between about 0.1 cm and 5 cm.
[0118] [00118] With reference now to Fig. 7, a perspective view of an absorbent article coated with the coating of the invention is shown. In particular, a coated cellulosic towel 500 is illustrated with the coating composition 510 printed along the central and liquid absorbing part of the towel, with uncoated parts 520 along the periphery of the towel.
[0119] [00119] The present invention has been described in a general and detailed way by means of examples. Those skilled in the art understand that the invention is not necessarily limited to the specifically described embodiments, but that modifications and variations can be made without departing from the scope of the invention, as defined by the following claims and their equivalents.

权利要求:
Claims (15)
[0001]
Composition of a coating sensitive to the aqueous medium for the triggered release of an active ingredient and visual indication of the presence of aqueous medium, characterized by the fact that it comprises: a betaine ester including a fragrance radical and having the formula:
[0002]
A water-sensitive coating composition according to claim 1, characterized in that the said color-changing visual moisture indicator consists of at least one pH indicator dye and a pH regulator.
[0003]
A water-sensitive coating composition according to claim 1, characterized by the fact that said fragrance radical is derived from the group of fragrances selected from thymol, vanillin, menthol and eugenol.
[0004]
A water-sensitive coating composition according to claim 1, characterized in that said composition includes at least one pH indicator dye, a pH regulator, a surfactant, and a binder.
[0005]
A water-sensitive coating composition according to claim 1, applied to an absorbent article, characterized by the fact that said article is preferably selected from the group consisting of care articles for babies, children, women, incontinence articles adult and absorbent cleaning articles.
[0006]
Aqueous-sensitive coating composition according to claim 5, characterized in that said absorbent article includes at least an upper layer, a lower layer and an absorbent central layer between said upper layer and the lower layer, and further wherein said coating composition is applied to at least one layer within said absorbent article.
[0007]
Aqueous-sensitive coating composition according to claim 5, characterized in that said absorbent article includes at least one peripheral side edge, and said coating composition is located adjacent to at least one peripheral side edge; or wherein each of said layers includes at least one peripheral side edge and said coating composition is applied adjacent to said peripheral side edge of at least one layer.
[0008]
Absorbent article, characterized in that it comprises at least one central absorbent layer, wherein said central absorbent layer includes the coating composition as defined in claim 1; and preferably wherein said central absorbent layer includes a peripheral side edge and said coating composition is applied to said central absorbent layer at least adjacent to said peripheral side edge.
[0009]
Absorbent article, characterized by the fact that it comprises at least an upper layer, a lower layer and an absorbent central layer having each insulting central deposition zone and at least one peripheral side edge, wherein said coating composition, as defined in claim 1, is applied to at least one of said top layer, bottom layer, central absorbent layer in said insulting central deposition zone or adjacent to at least one said peripheral side edge.
[0010]
Absorbent article according to claim 9, characterized in that said absorbent article includes a peripheral side edge and said coating composition is applied to a part of said absorbent article adjacent to said peripheral side edge; or wherein said top layer, bottom layer and the absorbent central layer each include a peripheral side edge, and said coating composition is applied beside at least one peripheral side edge of at least one of said top layer, bottom layer or absorbent central layer.
[0011]
Absorbent article according to claim 10, characterized in that said coating composition includes a color changing pH indicator dye and a pH regulator, and preferably wherein said coating composition includes a binder.
[0012]
Absorbent article according to claim 9, characterized in that said absorbent article includes a layer of said coating composition in at least two separate areas of said article.
[0013]
Absorbent article according to claim 9, characterized in that said absorbent article includes longitudinally directed peripheral side edges and front and rear peripheral side edges and said coating composition is applied adjacent to at least one of said longitudinally directed peripheral side edges and front and rear peripheral edges, and preferably wherein said coating composition is applied adjacent to each of said longitudinally directed peripheral side edges and said front and rear peripheral edges.
[0014]
Absorbent article, characterized in that it comprises at least one central absorbent layer, wherein said absorbent article including a longitudinally directed peripheral side edge, said absorbent article including an aqueous-sensitive coating composition as defined in claim 1, for the triggered release of active ingredients from said absorbent article, said aqueous-sensitive coating composition being affixed to said absorbent article adjacent to said longitudinally directed peripheral side edge.
[0015]
Absorbent article, characterized by the fact that it comprises at least an upper layer, a lower layer and an absorbent central layer, wherein said upper layer, absorbent central layer and lower layer, each includes a longitudinally directed peripheral side edge, said absorbent article including an aqueous-sensitive coating composition as defined in claim 1, for the triggered release of active ingredients from said absorbent article, said aqueous-sensitive coating composition being affixed to said absorbent article adjacent to said peripheral side edge longitudinally directed

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同族专利:

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公开号 | 公开日

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RU2014121796A|2015-12-20|

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CN103917205A|2014-07-09|

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BR112014011068B1|2021-06-29|

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WO2013070674A1|2013-05-16|

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KR20140097155A|2014-08-06|

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KR101491563B1|2015-02-11|

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US20130116644A1|2013-05-09|

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AU2012335289A1|2014-05-08|

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EP2775976B1|2018-05-30|

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CN103917205B|2016-12-14|

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AU2012335995A1|2014-05-08|

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KR20140090621A|2014-07-17|

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CN103917209A|2014-07-09|

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RU2014121797A|2015-12-20|

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AU2012335995B2|2016-11-03|

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BR112014011068A8|2017-06-20|

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EP2775976A4|2015-07-08|

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EP2782537A4|2015-08-19|

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AU2012335289B2|2015-02-05|

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BR112014011111A2|2017-05-16|

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RU2613781C2|2017-03-21|

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WO2013068859A1|2013-05-16|

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KR102009539B1|2019-08-09|

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MX2014005476A|2014-08-21|

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法律状态:
2018-12-04| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2019-10-15| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2020-11-10| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-01-12| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 07/11/2012, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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